Boyle's Law:
P1*V1=P2*V2
If you are at say, 50 feet down and the pressure is hypothetically 5 atm, and the volume of your lungs at that pressure is also 5 L.
If he goes to the surface, where the pressure is 1 atm, you get the following:
(5 atm)*(5 L) = (1 atm)*(X L)
X=25 L
His lungs would have expanded to 5 times their initial volume, that is why divers have to be so careful surfacing. If you don't exhale and be very careful your lungs can definitely explode.