ehhhh that doesnt make much sense.
the static and kinetic coefficients of friction are obviously completely different in any material. Trains dont slide along the tracks, like you would on a rail, so the friction coefficient wouldnt be the same in the two situations.
Also, last time I checked, temperature doesnt have an effect on friction unless it's to the extent that it could cause one substance to expand/contract or melt or something. but i do think rails can be stickier when they are warm, but i cant say why.
the oxidization/ rust theory could be valid too